DENIM

THE HISTORY OF DENIMS

A popular conception of the etymology of the word denim is that it is a contraction or derivative of the French term, serge de Nîmes. Denim was traditionally colored blue with indigo dye to make blue "jeans," though "jean" then denoted a different, lighter cotton textile; the contemporary use of jean comes from the French word for Genoa, Italy (Gênes), from which the first denim trousers were made. A similarly woven traditional American cotton textile is the diagonal warp-striped hickory cloth that was once associated with railroad men’s overalls, in which blue or black contrasting with undyed white threads form the woven pattern. Hickory cloth was characterized as being as rugged as hickory wood—not to mention the fact that it was deemed to be worn mainly by "hicks"—although neither may be the origin of that term [from a nickname for "Richard"]. Records of a group of New Yorkers headed for the California gold fields in 1849 show that they took along four "hickory shirts" apiece. Hickory cloth would later furnish the material for some "fatigue" pantaloons and shirts in the American Civil War.

• INTRODUCTION

Denim is a rugged cotton twill textile, in which the weft passes under two (twi- "double") or more warp fibers, producing the familiar diagonal ribbing identifiable on the reverse of the fabric.

• DENIM WASHING

Denim washing is the aesthetic finish given to the denim fabric to enhance the appeal and to provide strength. Dry denim, as opposed to washed denim, is a denim fabric that is not washed after being dyed during its production. Much of the appeal of dry denim lies in the fact that with time the fabric will fade in a manner similar to that which artificially distressed denim attempts to replicate. With dry denim, however, such fading is affected by the body of the person who wears the jeans and the activities of their daily life. This creates what many feel to be a more natural, unique look than pre-distressed denim.

DENIM WASHES ARE OF TWO TYPES: 1. Mechanical washes Stone washMicrosanding 2. Chemical washes Denim bleaching Enzyme wash Acid wash CHEMICAL WASHES

• Denim bleach

In this process a strong oxidative bleaching agent such as sodium hypochlorite or KMnO4 is added during the washing with or without stone addition.

Discoloration produced is usually more apparent depending on strength of the bleach liquor quantity, temperature and treatment time.

It is preferable to have strong bleach with short treatment time. Care should be taken for the bleached goods so that they should be adequately antichlored or after washed with peroxide to minimize yellowing. Materials should be carefully sorted before processing for color uniformity.

Limitations: -Process is difficult to control i.e. difficult to reach the same level of bleaching in repeated runs. -When desired level of bleaching reached the time span available to stop the bleaching is very narrow. Due to harshness of chemical, it may cause damage to cellulose resulting in severe strength losses and/or breaks or pinholes at the seam, pocket, etc. -Harmful to human health and causes corrosion to stainless steel. -Required antichlor treatment. -Problem of yellowing is very frequent due to residual chlorine. -Chlorinated organic substances occur as abundant products in bleaching, and pass into the effluent where they cause severe environmental pollution. Enzyme Wash

It is environmentally friendly wash. It involves the Application of organic enzymes that eat away at the fabric, i.e. the cellulose. When the desired color is achieved, the enzymes can be stopped by changing the alkalinity of the bath or its temperature. Post treatment includes final rinsing and softening cycle. The effects produced by the cellulose enzyme are---

1.Use of cellulase making the seams, hems, and pockets more noticeable 2.Salt pepper effect is color contrast effect. 3.Faded garment with acid cellulase enzyme provides less color contrast in proportion to garment washed with neutral cellulase enzymes. Garment load size of the machine is 35-40 jeans per machine and it cannot be overloaded. Acid wash

It is done by tumbling the garments with pumice stones presoaked in a solution of sodium hypochlorite or potassium permanganate for localized bleaching resulting in a non uniform sharp blue/white contrast. In this wash the color contrast of the denim fabric can be enhanced by optical brightening. The advantage of this process is that it saves water as addition of water is not required. Process cycle

Limitations of acid wash: -Acid washed, indigo dyed denim has a tendency to yellow after wet processing. -The major cause is residual manganese due to incomplete neutralization, washing or rinsing. Remedy: -Manganese is effectively removed during laundering with addition of ethelene-diamine-tetra-acetic acid as chelating agent. -Acid washing jeans avoided some of problems of stone wash, but came with added dangers, expenses, and pollution.

MECHANICAL WASHES

Stone wash:

In the process of stone washing, freshly dyed jeans are loaded into large washing machines and tumbled with pumice stones to achieve a soft hand and desirable look. Variations in composition, hardness, size shape and porosity make these stones multifunctional. The process is quite expensive and requires high capital investment. Pumice stones give the additional effect of a faded or worn look as it abrades the surface of the jeans like sandpaper, removing some dye particles from the surfaces of the yarn.

Selection of stone

Stone should be selected of the proper hardness, shape, and size for the particular end product. It should be noted that large, hard stones last longer and may be suited for heavy weight fabrics only. Smaller, softer stones would be used for light weight fabrics and more delicate items. Stone wt. /fabric wt. = 0.5 to 3 /1 It depends on the degree of abrasion needed to achieve the desired result. Stones can be reused until they completely disintegrate or washed down the drain.

Problems caused by stones: -Damage to wash machineries and garment due to stone to machine and machine to stone abrasion -Increase in labor to remove dust from finished garments. -Water pollution during disposal of used liquor. -Back staining and re deposition. Back staining or Re-deposition:

The dye removed from denim material after the treatment with cellulose or by a conventional washing process may cause "back staining” or "redeposition”. Re-coloration of blue threads and blue coloration of white threads, resulting in less contrast between blue and white threads.

Remedy of back staining -Adding dispersion/suspension agent to wash cycle. -Intermediate replacement of wash liquor. -Using alkaline detergent like sodium per borate with optical brightener as after wash. Limitations of stone washing: -Quality of the abrasion process is difficult to control Outcome of a load of jeans is never uniform, little percentage always getting ruined by too much abrasion. -The process is non-selective. -Metal buttons and rivets on the jeans in the washing machines get abraded. -This reduces quality of the products and life of equipment, and increases production costs. -Stones may turn into powder during the process of making the garment grayish in color and rough too -Provides rougher feel than enzyme wash -Stone may lead the harm to the machine parts Microsanding There are 3 ways for this technique: •Sandblasting •Machine sanding •Hand sanding or hand brushing Used in various ways: -Flat surfaces (tables, ironing boards) -On the dummy (inflatable dummies, sometimes standing, sometimes flat, sometimes 'seated') -Various Used in various ways: -Flat surfaces (tables, ironing boards) -On the dummy (inflatable dummies, sometimes standing, sometimes flat, sometimes 'seated') -Various templates can be used to create a 3D effect. SAND BLASTING Sand blasting technique is based on blasting an abrasive material in granular, powdered or other form through a nozzle at very high speed and pressure onto specific areas of the garment surface to be treated to give the desired distressed/ abraded/used look. - It is purely mechanical process, not using any chemicals. - It is a water free process therefore no drying required. - Variety of distressed or abraded looks possible. - Any number of designs could be created by special techniques. WHISKERING -Also known as ‘Cat's Whiskers’ -Crease lines around the crotch. -Industrially done with laser, sandblasting, machine sanding, hand sanding and abrasive rods. -Also used for 'knee whiskers' (whiskers on the sides of knees) and 'honeycombs' (crease marks on the back of the knee) Other chemical washes: •Rinse wash •Cellulase wash •Ozone fading •Snow wash •Salt water denim •Flat finish •Over dye •Sun washing •Super dark stone RINSE WASH -Chemically bleaching jeans so that the color fades away -Breaks down the fibers of jeans and creates white streaks or spots on denim -Gives a unique rugged look, also called snow wash -Earlier involved the use of pumice stone -Presently process involves spraying chemical and removing it immediately -Come in colors like blue, black, green, brown, grey etc. CELLULASE WASH -This is done to achieve a wash down appearance without the use of stones or with reduced quantities of stones. -Cellulase enzymes are selective only to the cellulose and will not degrade starch. -Under certain conditions, their ability to react with cellulose (cotton) will result in surface fiber removal (weight loss). -This will give the garments a washed appearance and soft hand. Factors influencing cellulase performance -pH -Temperature -Time -Dose -Mechanical action OZONE FADING -By using this technique, the garment can be bleached. -Bleaching of denim garment is done in washing machine with ozone dissolved in water. -Denim garments can also be bleached or faded by using ozone gas in closed chamber. -In the presence of UV light, there is an interaction between the hydrocarbons, oxides of nitrogen and oxygen that causes release of ozone. -Indigo dyestuff tends to fade or turn yellow due to ozone reaction. The advantages associated with this process are: -Color removal is possible without losing strength. -This method is very simple and environmentally friendly because after laundering, ozonized water can easily be deozonized by UV radiation. FLAT FINISH

It is a special process done to impart fabric with an even wash down effect and very clean surface. Originally liquid ammonia was used, but now use mercerization plus calendering processes to achieve the flat surface. Mercerization swells up the cotton fibers and allows the calendering to press flat the surface. They consider this as an imitation process to the use of ammonia, which is toxic and not allowed in commercial use in most countries

OVERDYE -Dyeing over the fabric or jeans to add another tone of color -Most often used is a 'yellowy' overdye to create a 'dirty' look -Also can be applied with spray gun or paintbrush for local coloring SUNWASHING -A very light shade by bleaching and stoning -Looks as if the sun faded the fabric SUPER DARK STONE -Commercial term for an extra dark indigo color -Results from a double-dyeing technique SNOW WASH DENIM Denim treated with a variation of acid wash that imparts bright white highlights. QUICK WASH DENIM •Aims at minimizing wash cycle time •Results in more economical washes and solving many other washing problems faced by launderes during fashion wash cycles •The yarns are ring dyed using indigo giving 25 to 30% less fixed dye to obtain a given shade •During wash cycle,indigo dye can be removed quickly,giving washed look Advantages of quick wash denim 1. Streaks develop in garments after washing process due to differences in dye concentration of denim fabrics are avoided using a modified alkali-ph controlled system giving uniformity of shade. 2. Amount of indigo dye required is less thus making it an economical process 3. Time required for washing is 20-30% less than that required for conventional denim. 4. Lesser enzymes and oxidising agent used 5. Environment friendly process 6. Back staining is minimised due to less concentration of of indigo dye in the wash liqour. Other Other Mechanical washing Whiskering Shot gun denim Water jet fading Super stone wash Ice wash Thermo denim Laser technology finish WATERJET FADING -Hydrojet treatment is used for enhancing the surface finish, texture, durability of denim garment. -Hydroject treatment involves exposing one or both surfaces of the garment through hydrojet nozzles. -The degree of colour washout, clarity of patterns, and softness of the resulting fabric are related to the type of dye in the fabric and the amount and manner of fluid impact energy applied to the fabric. -As this process is not involved with any chemical, it is pollution free. LASER TECHNOLOGY -It is a computer controlled process for denim fading. -This technique enables patterns to be created such as lines and/or dots, images, text or even pictures. -It is water free fading of denim. -Being an automatic system, chances of human error are slim. -Also called spray painting in denims. -This technique has relatively high cost. SUPER STONEWASH -Prolonged stonewashing, up to six hours or more. ICE WASH -Ice washing in denim fabrics is done to remove more than half the dye during washing THERMO-DENIM Also called double denim. A lightweight fabric (either plain, fancy or colored) is glued to the denim. The glue comes off after washing and the trousers look like they've been lined VINTAGE −Applies heavy stonewashing or a cellulose enzyme wash, with or without bleach −Gives an old and worn look CHEMICALS ON DENIMS 1.Bleach fast Indigo −Value addition to denim −Retains indigo on certain parts −Kind of resist effect −Chemical applied by brush, cured at 150ºC −Ex. Indigofix AXN 2. Anti-depositing agent −Prevents “back staining” of fabric by loose indigo during washing −Improves contrast in denim −Used in stone wash step 3. Dye stuffs with softener −To carry dyeing and softening in one step −Soft and supple hand −Saves time, money and energy as added to final rinse −Gives used and worn out effect 4. Anti creasing agent −Provides fabric to fabric lubrication −Prevents formation of crack marks and streaks −Minimizes abrasion and gives strength 5. Wrinkle formation −Creating smooth and permanent wrinkle −Cross linking concept −Ex. DMDHEU −White pigment −Can be applied by brush, spray or screen −Then cured at 150ºC −Washed and treated with softener 6. White pigment •Can be applied by brush, spray or screen •Then cured at 150ºC •Washed and treated with softener CONCLUSION

Denim is unique in its singular connection with one colour. The warp yarn is traditionally dyed with the blue pigment obtained from indigo dye. Until the introduction of synthetic dyes, at the end of the 19th century, indigo was the most significant natural dye known to mankind, linked with practical fabrics and work clothing. The durability of indigo as a color and it's darkness of tone made it a good choice, when frequent washing was not possible. The old mass market has segmented, fragmented, shattered into a multitude of mini, micro and niche markets. The last generation has a vast quantity of brands to choose from, a different perception of the cult value of owning small insider labels and a fanatical loyalty only to what's hot on a daily basis. Freed of all social and creative restrictions, denim is assuming any number of disguises and contexts to be worn in and has broken through almost any limitation on price. It can also be found in home collections, appearing in cushions, bed spreads and furniture-coverings.